#! perl -slw
use strict;
use Data::Dump qw[ pp ];

my @keys = unpack 'A8xA6xA3xA10xA5', scalar <DATA>;
<DATA>; ## discard
my @data = map{
    my %hash;
    @hash{ @keys } = unpack 'A8xA6xA3xA10xA5', $_;
    \%hash;
} <DATA>;

pp \@data;

__END__
Name     UPP    Age Career     Terms
-------- ------ --- ---------- -----
Rejnaldi 765987 38  Citizen    6
Lisandra 6779AA 34  Noble      4
Kuran    899786 42  Marine     8