use Win32API::File qw (:Func );

my ( $sRootPath, $osVolName, $lVolName, $ouSerialNum, $ouMaxNameLen, $ouFsFlags, $osFsType, $lFsType );

$sRootPath = "C:/";

GetVolumeInformation( $sRootPath, $osVolName, $lVolName, $ouSerialNum, $ouMaxNameLen, $ouFsFlags, $osFsType, $lFsType );

#----
print "\nRoot:\t$sRootPath\n";
print "VolName:\t$osVolName\n";
print "SerialNumber:\t$ouSerialNum\n";
printf "Hex SerialNumber:\t%x\n", $ouSerialNum;

##</code><code>##

Root:   C:/
VolName:        mecano
SerialNumber:   2226596281
Hex SerialNumber:       84b729b9

##</code><code>##

 >vol c:
 Volume in drive C is mecano
 Volume Serial Number is 84B7-29B9