ttys = ( );

open(WHO, "who|")                   or die "can't open who: $!";
while (<WHO>) {
    ($user, $tty) = split;
    push( @{$ttys{$user}}, $tty );
}

foreach $user (sort keys %ttys) {
    print "$user: @{$ttys{$user}}\n";
}
The heart