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C:/Perl64.v.5.14/bin\perl.exe -w c:/Projects/LWP/test.lwp.pl https://w
+ww.google.ca
2012/11/28 20:13:53> Request: POST https://www.google.ca,    User-Agen
+t: libwww-perl/6.02,    Content-Length: 0,    Content-Type: applicati
+on/x-www-form-urlencoded,    (no content)
2012/11/28 20:13:53> Response last request: https://www.google.ca
...
Header field names: Content-TypeClient-DateClient-Warning
Previous: undef
2012/11/28 20:13:53> The URL https://www.google.ca was not successfull
+y retrieved.

$ua->ssl_opts( SSL_ca_file => Mozilla::CA::SSL_ca_file() );
$ua->ssl_opts( verify_hostnames => 0 );