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use IO::Socket::SSL qw( SSL_VERIFY_NONE );
use RPC::XML::Client;
...
                          SSL_verify_mode => SSL_VERIFY_NONE
                                         }
                );

my $session = $client->simple_request('login', 1, 0,$user, $password);

*******************************************************************
 Using the default of SSL_verify_mode of SSL_VERIFY_NONE for client
...
 SSL_verify_mode explicitly to SSL_VERIFY_NONE in your application.
*******************************************************************
at C:/strawberry/perl/site/lib/LWP/Protocol/http.pm line 31