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#!/usr/bin/env perl

...
print "\nData::Dump Output:\n";
use Data::Dump;
dd \%go_hash;

Symbol1    H1SXX9    Homo Sapiens    GO:0015031    protein transport
Symbol2    H1SXZ5    Homo Sapiens    GO:0003824    catalytic activity
...
Symbol4    H1SY02    Homo Sapiens    GO:0015031    protein transport
Symbol5    H1SY06    Homo Sapiens    GO:0004129    cytochrome-c oxidas
+e activity
Symbol5    H1SY06    Homo Sapiens    GO:0005506    iron ion binding

Data::Dumper Output:
$VAR1 = {
...
               },
             },
}