If you have some time to invest, I would go for DocBook.
The html Version of
DocBook: The Definitive Guide by
Norm Walsh and Leonard Muellner (O'Reilly, 1999)
is available for free at
O'Reilly's page,
for easy browsing, or as a zipped download from
docbook.org
(html or sgml). Browsing a while through
DocBook: The Definitive Guide
should give you enough information to decide, wether this
kind of encoding is the right stuff for you.
Hanamaki