You have a number of syntax errors. Lets look at the first few lines of your while loop.

while (my \@row = $sth->fetchrow_array) {
    print "<table id="t01">";
    print "<tr>";
    if (row[0] eq '1') {
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my \@row is wrong. It should be my @row.
print "<table id="t01">"; has a quoting error. You need to either escape the inner double quotes in id="t01" or use single quotes like this id='t01'.
if (row[0] eq '1') is missing the $ on the $row[0] var

When I see a repeating pattern I think 'can I loop this ?'

my @stat = (
  ['trunk_usage'  ,'% Trunk Usage'],
  ['pre_ivr'      ,'Pre-IVR Call Volume'],
  ['trunk_group'  ,'Trunk Group Utilization'],
  ['average_speed','Average Speed of Answer'],
  ['outage_call'  ,'Outage Call Volume'],
  ['ivr_call'     ,'IVR Call Volume'],
  ['non_outage'   ,'Non-Outage Call Volume'],
  ['post_ivr'     ,'Post-IVR Call Volume'],);

my @row = (1,0,1,1,1,0,1,0); 
#while (my @row = $sth->fetchrow_array) {
  print qq!<table id="t01"><tr>!;    
  for my $i (0..$#stat){
    my $chk = ($row[$i] == 1) ? 'checked' : '';
    print qq!<td>
      <input type="checkbox" name="$stat[$i][0]" value="1" $chk />
      $stat[$i][1]
      </td>!;
    if (($i % 2) && ($i < $#stat)){
      print q!</tr><tr>!;
    }
  }
  print q!</tr></table>!;
#}

print q!</div></body></html>!;
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