binmode STDIN, ':utf8';
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See Encode, as well as perlunitut and perluniintro.

But the data shown doesn't seem to be unicode. If it was, this

DepM-ssito Centralizado
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would instead be

DepM-CM-3sito Centralizado
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So, the data is some ISO-8859 variant. In ISO-8859 the ó is chr(243), which is chr(ord ('s') | 128) (hence the output as M-s) and the character with the high bit set in

London andM-  NewYork
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is most likely chr(160), i.e. a non-breaking space - chr(ord (' ') | 128).