Like this? Works fine.

#!/usr/bin/perl

# http://perlmonks.org/?node_id=1188504

use strict;
use warnings;

my %hash = qw( title1 one title3 three title4 four title2 two );

my @labels = sort keys %hash;

my @content = @hash{@labels};

use Data::Dumper;
print Dumper \%hash;
print "\n";
print Dumper \@labels;
print "\n";
print Dumper \@content;
[download]

This could work. I'm going to try and implement it tonight

... what if the content for each element of that array is a string of characters and not numeric?

One interpretation:

c:\@Work\Perl\monks>perl -wMstrict -le
"use Data::Dump qw(dd);
 ;;
 my %hash = qw(title1 uno  title3 tres  title4 quatro  title2 dos);
 ;;
 my @labels  = sort keys %hash;
 my @content = @hash{@labels};
 ;;
 dd \%hash;
 dd \@labels;
 dd \@content;
"
{ title1 => "uno", title2 => "dos", title3 => "tres", title4 => "quatr
+o" }

["title1", "title2", "title3", "title4"]

["uno", "dos", "tres", "quatro"]
[download]

Update: The  @hash{@labels} thing is a hash slice.

Hash slices are a new concept for me but I will give this a try as well as the other suggestions everyone has added here