No.

Your talk of "memory addresses" suggests to me that you are coming from a C mindset to Perl. I will try to explain this in terms of malloc:

Think of my as malloc:

SV* Array_Vals = malloc();
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Think of push @Array_of_ALL_Vals, \@Array_Vals as Array_of_ALL_Vals[ iloop ] = Array_Vals;.

Then your Perl code looks like this translated to "C":

AV* Array_of_ALL_Vals;
for my $iloop (0 .. 10){
    SV* Array_Vals = malloc(); // actually, newAV()
    .
    Code in here to populate @Array_of_Vals
    .
    Array_of_ALL_Vals[ iloop ] = Array_Vals;
}
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Deallocating that memory again is some of the magic that Perl provides.