The /g modifier when used in conjunction with an if is a little unusual. Typically you would see things like 'if (s/x/y/g)' or 'if (/x/)'. The /g means to do a global match, and it will return an array of applicable matches, if given the opportunity.
Maybe you are intending to write something like this:
open(INPUT, "ml_test.html");
# Read in the entire file into a single string.
my $text = join ('', <INPUT>);
close(INPUT);
while ($text =~ /\bclb_new>\b(.*?)\b<\/a>/g)
{
print $1;
}