Hi Rahul Gupta,

Really, I don't know how you wanted your hash sorted but I guess you would like to sort using "keys" since, your values from your OP are "kind" of sorted, following the numbers on the names like UEH1_system_ip, UEH11_system_ip,.. etc.
The following shows one way of doing it:

use warnings;
use strict;

my %ip_store = (
    "11.0.0.1"  => "UEH1_system_ip",
    "11.0.0.11" => "UEH11_system_ip",
    "11.0.0.3"  => "UEH25_system_ip",
    "11.0.0.25" => "UEH111_system_ip"
);

my @ip_data =
  map  { $_->[0] }
  sort { $a->[1] <=> $b->[1] }
  map  { /\.([0-9]+)$/; [ $_, $1 ] } keys %ip_store;

print $ip_store{$_}, $/, $_, $/ for @ip_data;
[download]

UEH1_system_ip
11.0.0.1
UEH25_system_ip
11.0.0.3
UEH11_system_ip
11.0.0.11
UEH111_system_ip
11.0.0.25
[download]