If you don't need to keep the K or R items on which to cut the string, you could try this (demonstrated under the Perl debugger):
DB<6> $p = 'ALTAMCMNVWEITYHKGSDVNRRASFAQPPPQPPPPLLAIKPASDASD';
DB<7> @b = split /[KR](?!P)/, $p;
DB<8> x \@b;
0 ARRAY(0x6004f0f88)
0 'ALTAMCMNVWEITYH'
1 'GSDVN'
2 ''
3 'ASFAQPPPQPPPPLLAIKPASDASD'
If you need to keep those K and R items, then this might be easier:
DB<10> p $p
ALTAMCMNVWEITYHKGSDVNRRASFAQPPPQPPPPLLAIKPASDASD
DB<11> $p = 'ALTAMCMNVWEITYHKGSDVNRRASFAQPPPQPPPPLLAIKPASDASD';
DB<12> $p =~ s/([KR])(?!P)/$1=/g;
DB<21> p $p
ALTAMCMNVWEITYHK=GSDVNR=R=ASFAQPPPQPPPPLLAIKPASDASD
In the latter case, you can then just split the resulting string on
/=/.
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