These are what I'm using. That last entry is potentially significant.

Perl	5.20.3
LWP::UserAgent	6.15
LWP::Protocol	6.15
IO::Socket	1.38
IO::Socket::SSL	2.012
Mozilla::CA	20141217

If I were you these are the steps I would take:

• Install version 20141217 of Mozilla::CA and test with that.
• Enable debugging (via IO::Socket::SSL) and see the detail behind the connection failure.

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