you can try below if you are not doing SSL validation,
untested though since I do not have permission to install Net::SSL module in my box
use strict;
use warnings;

use LWP::UserAgent;
use HTTP::Request::Common qw(GET);
use Net::SSL;

my $ua = LWP::UserAgent->new(ssl_opts => { verify_hostname => 0}, );

my $req = GET 'https://ptabdata.uspto.gov/ptab-api/documents';
my $res = $ua->request($req);

if ($res->is_success) {
    print $res->content;
}else{
    print $res->status_line . "\n";
}

[download]

In reply to Re: Can't connect to https using LWP::UserAgent by madtoperl
in thread Can't connect to https using LWP::UserAgent by ruqui

Title:
Use:  <p> text here (a paragraph) </p>
and:  <code> code here </code>
to format your post, it's "PerlMonks-approved HTML":


  • Posts are HTML formatted. Put <p> </p> tags around your paragraphs. Put <code> </code> tags around your code and data!
  • Titles consisting of a single word are discouraged, and in most cases are disallowed outright.
  • Read Where should I post X? if you're not absolutely sure you're posting in the right place.
  • Please read these before you post! —
  • Posts may use any of the Perl Monks Approved HTML tags:
    a, abbr, b, big, blockquote, br, caption, center, col, colgroup, dd, del, details, div, dl, dt, em, font, h1, h2, h3, h4, h5, h6, hr, i, ins, li, ol, p, pre, readmore, small, span, spoiler, strike, strong, sub, summary, sup, table, tbody, td, tfoot, th, thead, tr, tt, u, ul, wbr
  • You may need to use entities for some characters, as follows. (Exception: Within code tags, you can put the characters literally.)
            For:     Use:
    & &amp;
    < &lt;
    > &gt;
    [ &#91;
    ] &#93;
  • Link using PerlMonks shortcuts! What shortcuts can I use for linking?
  • See Writeup Formatting Tips and other pages linked from there for more info.