Sounds like homework to me ...

You could always use an archiving tool to compress all of the files and span them to the desired media size. I brushed off a version of pkzipc (on windows) and had a play. The following command compresses the data and creates a number of 700Mb files suitable for dropping onto CD.
pkzipc -add -span=1.44 c:save.zip *.doc

Similar opportunities exist with tar on UNIX systems.

In reply to Re: How to maximise the content of my data CD by inman
in thread How to maximise the content of my data CD by amaguk

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