If you are sending mail with a script, and have something like print(MAIL "To: someone\@somewhere.someorg\n"); the @ needs to be escaped. Of course, one could use single quotes here (except for the newline), but one might want to store the address in a variable and have that and some other things interpolated, and then the @ may cause problems if it's not escaped. It is often possible to get around that with some cleverness, but sometimes it's easier to just escape the troublesome characters.
(At least, that's what I imagine the OP might be dealing with.)
(Update: After thinking about it for a while, I can't really think of a convincing reason to escape the @. My brain is just not working well today...please ignore me! I'll shut up for the rest of the day.)

In reply to Re^2: Having a problem replacing "@" with "\@" by chas
in thread Having a problem replacing "@" with "\@" by TASdvlper

Title:
Use:  <p> text here (a paragraph) </p>
and:  <code> code here </code>
to format your post, it's "PerlMonks-approved HTML":



  • Posts are HTML formatted. Put <p> </p> tags around your paragraphs. Put <code> </code> tags around your code and data!
  • Titles consisting of a single word are discouraged, and in most cases are disallowed outright.
  • Read Where should I post X? if you're not absolutely sure you're posting in the right place.
  • Please read these before you post! —
  • Posts may use any of the Perl Monks Approved HTML tags:
    a, abbr, b, big, blockquote, br, caption, center, col, colgroup, dd, del, details, div, dl, dt, em, font, h1, h2, h3, h4, h5, h6, hr, i, ins, li, ol, p, pre, readmore, small, span, spoiler, strike, strong, sub, summary, sup, table, tbody, td, tfoot, th, thead, tr, tt, u, ul, wbr
  • You may need to use entities for some characters, as follows. (Exception: Within code tags, you can put the characters literally.)
            For:     Use:
    & &amp;
    < &lt;
    > &gt;
    [ &#91;
    ] &#93;
  • Link using PerlMonks shortcuts! What shortcuts can I use for linking?
  • See Writeup Formatting Tips and other pages linked from there for more info.