HomeDirectory is proably a property, not a method, so 
$User->HomeDirectory("\\server\homeshare");

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should be 
$User->{HomeDirectory} = "\\\\server\\homeshare";

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Win32::OLE uses a lot of AUTOLOAD magic, so both might be exchangeable. Well, at least, I do think the accessor version of the property without parameters, is equivalent to just reading the property: 
$home = $User->HomeDirectory();

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vs. 
$home = $User->{HomeDirectory};

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In reply to Re^2: Update HomeDirectory Using Win32::Ole by bart
in thread Update HomeDirectory Using Win32::Ole by Anonymous Monk

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