you should list perl58.lib in your command line? 
gcc.exe "C:\test\start.c" -o "C:\test\start.exe" -I"C:\Dev-Cpp\include
+" -I"C:\Perl\lib\CORE" -L"C:\Perl\lib\CORE" -L"C:\Dev-Cpp\lib" perl58
+.lib

[download]

And here's many information on using gcc for compiling modules with activestate perl here, on PM

In reply to Re^8: problem with par as other user by vkon
in thread problem with par as other user by Anonymous Monk

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