It may be too late for this question,but the below link shows a sample about how to send an email by NET::SMTP. http://www.perlmonks.org/?node_id=837884

In Window32,there is no native command email client to be used,POP3 of Windows2003 may be the only tool.If you have installed IIS or Outlook(Outlook express is limited) ,Try WIn32::OLE to send a mail.

In reply to Re: Sending Mail trough Perl using ActivePerl on windows by camenix
in thread Sending Mail trough Perl using ActivePerl on windows by the_hawk_1

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