This is a "zero-width, look-behind assertion". The assertion is true if (?<!/) does not immediately follow a '/' (forward slash) character at the point at which the assertion occurs in the regex.
See (?<!pattern) in the Extended Patterns section (in the Look-Around Assertions subsection) of perlre.
Update: Added "zero-width" to description.
In reply to Re^3: Getting around "/" as a word boundary
by AnomalousMonk
in thread Getting around "/" as a word boundary
by sherab
| For: | Use: | ||
| & | & | ||
| < | < | ||
| > | > | ||
| [ | [ | ||
| ] | ] |