$1 does not contain what you think it does. If you modify your code to wrap your output in a delimiter: 
use strict;

my %h = (a1 => 1);

my $test = "a1 to a2";

if ($test =~ /([a-hA-H][1-8]\s*)to(\s*[a-hA-H][1-8])/)
{
    print "test work\n"; 
}

print "x$h{$1}x\n"; #print nothing
print "x$h{a1}x\n"; #print 1

print "x$1x\n"; #print "a1"

[download]
you get: 
test work
xx
x1x
xa1 x

[download]

You are grabbing whitespace in addition to your square id. You'll get your expected result if you modify your regular expression to:

/([a-hA-H][1-8])\s*to\s*([a-hA-H][1-8])/

In reply to Re: Weird hash access problem by kennethk
in thread Weird hash access problem by tehjord

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