Easy:

@list = qw(this that and another);
@array = ([@list], [1, 2, 3]);

#value of $array[0][2] is now 'that'
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You can then reference the internal arrays as you would any multidimensional array.
The thing to keep in mind here is that hashes and arrays can only keep scalar values- so referencing

@array
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is doing it in list mode.

[@array]
\@array
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is fetching it as a reference. Keep in mind that that \@array is only a shallow copy- modifying the value in a dereferenced context will modify @array itself, where as modifying the value of [@array] will keep @array untouched.