I assume you just want the name/path pairs:

use strict;
my $config = "path_to_your_conf_file";
open(CONFIG, "<$config") or die "Can't open $config\n";
while(<CONFIG>){
   if(/(\w+):(\w+)/){
     # now do your copy,
     # there is some work, if these are in different servers.
   }
}
close(CONFIG);
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