It's kind of funny, because my feelings are the opposite of what blokhead describes in the last paragraph of Re^3: Representing all data as Lists; I'd actually be more inclined to support unifying the internals than changing the interface, though I don't really think either is a very good idea.
Like I said (or maybe I should have said more clearly) in my original reply, I think different things should look different. You may say the corollary is that alike things should like similar -- and I'd agree -- but in this case I dont' think a string and a list are things that are really all that alike. I can understand why someone would say they are, but I think it's a contrived likeness.
I strongly agree with Perl's current notion that a string is an individual thing (i.e. a scalar). I don't often have the need to break that thing apart and operate on its individual characters (Update: a clarification of what I meant). Perhaps that's a learned trait, but I tend to think it's more likely that instinctively seeing a string as a list is less natural.
In the case of hashes, I don't feel as strongly as I do about strings. Hashes are very list-like already, and as you pointed out, you can already coerce a list into a hash. That's a pretty natural-feeling thing, in my eyes. I still think a hash is different enough from a plain list that it deserves its own syntax and sigil, though. And Perl 6 will make it pretty easy to get a list of pairs, or a list of interwoven keys/values:
my %hash = <one 1 two 2 three 3>;
say $_.join(" ") for %hash.pairs;
# output:
# one 1
# three 3
# two 2
say for %hash.kv;
# output:
# one
# 1
# three
# 3
# two
# 2
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