Yes, it is. Reading text files is simple, and there are lots of good modules out there for reading XML files, like XML::LibXML or XML::Twig.
If you don't know any perl, reading perlintro should help you. If you have more specific questions, feel free to ask (but show us what you've tried, and tell us how it did not match your expectations).
Perl 6 - links to (nearly) everything that is Perl 6.
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I would recommend storing each of your "dictionary" words in an associative array (hash), incrementing the value each time the word is found. Once all your XML files have been parsed, it is a simple matter to print each key and value from the hash.
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