shawshankred: From your example, you seem to want the keys printed in alpha order. As a convenience, this approach uses a temporary hash reference for the particular hash sub-element you wish to print; of course, it also would be possible (but, IMO, less readable/maintainable) to always access needed elements from the top of the hash down. (The structure of the example HoH I used is less complex than that in the OP, but you get the idea.)

>perl -wMstrict -le
"my %VeCog = (
   Operations => {
     A => {
       Value => '1',
       Desc  => 'Minmess',
       },
     B => {
       Value => '10',
       },
     C => {
       Value => '100',
       },
     D => {
       Value => '1000',
       },
     },
   );
 my $tmp_hashref = $VeCog{Operations};
 for my $key (sort keys %$tmp_hashref) {
   print qq{$key:$tmp_hashref->{$key}->{Value}};
   }
"
A:1
B:10
C:100
D:1000
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Update: Also, take a look at the HASHES OF HASHES section ( Access and Printing of a HASH OF HASHES subsection) of the Data Structures Cookbook, perldsc.