Your code, as you wrote above in html, is missing all the brackets needed to specify array elements. The code I believe you meant to post, as reconstructed by me, is shown below. I had to remove your resizable and geometry lines to get the Entries to show up, and I made the bg color white on the Entries for ease of visibility.

As far as getting focus to shift the way you want, I'm stumped, maybe a smarter monk may know. It may be in the way Table is designed. An alternative would be to use TableMatrix, see the second code example below.

Your corrected, runnable code:

#!/usr/bin/perl 
use Tk; 
use Tk::Entry; 
use Tk::Table; 
use Tk::LabFrame; 
use warnings; 
use strict; 

my $v="0.00"; 
my $mw = MainWindow->new; 
#$mw->geometry("200x200"); 
#$mw->resizable(0,0); 
$mw->title("Table Example");
 
my @id=qw/100 101 102 103 104 105 106 107 108 109 110/; 
my @name=qw/AAA BBB CCC DDD EEE FFF GGG HHH III JJJ KKK/; 
my @top2=qw/No Name Amount/; 

my $table_frame = $mw->LabFrame()->pack(); 
my $table = $table_frame->Table(-columns => 10, -rows => 6, 
                  -fixedrows => 1, -scrollbars => 'oe', 
                  -relief => 'raised',-background=>'white'); 

my $j=0; my $i=0; 

foreach my $j(1..11) { 

my $tmp_label=$table->Label(-text => $id[$i], 
           -width => 8, -relief =>'raised'); 

my $tmp_label1 = $table->Label(-text => $name[$i], 
           -width => 8, -relief =>'raised'); 

my $tmp_label2= $table->Entry( -width => 8, -relief =>'raised',
       -bg => 'white',
       -validate=>'key',-validatecommand=>sub{ $_[1] =~m/\d\d/} ,
       -invalidcommand=>sub{$mw->bell} ); 

$tmp_label2->bind('Tk::Entry','<Return>',sub{shift->focusNext}); 

$table->put($j,1,$tmp_label); 
$table->put($j,2,$tmp_label1); 
$table->put($j,3,$tmp_label2); 
$i++; 
} 

$table->pack(); 
my $button_frame = $mw->Frame( -borderwidth => 4 )->pack(); 
$button_frame->Button(-text => "Exit", -command => sub {exit})->pack()
+; 

MainLoop;
[download]

An alternative using TableMatrix, in which focus is passed the way you want by tabbing:

#!/usr/bin/perl
use Tk;
use Tk::TableMatrix;
 use warnings;
use strict;

my $mw = MainWindow->new;
my $table = $mw->Scrolled("TableMatrix",
              -resizeborders=>'both',
              -titlerows => 1,
              -rows => 20,
              -colstretchmode=>'all',
              -cols => 3,
              -cache => 1,
             -scrollbars => "osoe");

for(my $row = 1; $row < 20; $row++) {

        my $entry = $table->Entry(-bg=>'white');
    
        $table->windowConfigure("$row,5", -window => $entry);

}

$table->set("0,0", "Col 1");
$table->set("0,1", "Col 2");
$table->set("0,2", "Col 3");
$table->set("0,3", "Col 4");
$table->set("0,4", "Col 5");

$table->pack(-expand => 1,
                         -fill => 'both');

MainLoop;
[download]

#!/usr/bin/perl 
use Tk; 
use Tk::Entry; 
use Tk::Table; 
use Tk::LabFrame; 
use warnings; 
use strict; 

my $v="0.00"; 
my $mw = MainWindow->new; 
$mw->geometry("250x400"); 
#$mw->resizable(0,0); 
$mw->title("Table Example");
 
my @id=qw/100 101 102 103 104 105 106 107 108 109 110/; 
my @name=qw/AAA BBB CCC DDD EEE FFF GGG HHH III JJJ KKK/; 
my @top2=qw/No Name Amount/; 

my $table_frame = $mw->LabFrame()->pack(-expand=>1, -fill=>'both'); 

my $table = $table_frame->Table(-columns => 10, -rows => 6, 
                  -fixedrows => 1, -scrollbars => 'oe', 
                  -relief => 'raised',-background=>'white'); 

my $j=0; my $i=0; 

my @ents;

foreach my $j(1..11) { 

my $tmp_label=$table->Label(-text => $id[$i], 
           -width => 8, -relief =>'raised'); 

my $tmp_label1 = $table->Label(-text => $name[$i], 
           -width => 8, -relief =>'raised'); 

my $tmp_label2= $table->Entry( -width => 8, -relief =>'raised',
       -bg => 'white',
       -validate=>'key',
       #-validatecommand=>sub{ $_[1] =~m/\d\d/} ,
       #-invalidcommand=>sub{$mw->bell} 
       ); 

#$tmp_label2->bind('Tk::Entry','<Return>',sub{ shift->focusNext }); 

$table->put($j,1,$tmp_label); 
$table->put($j,2,$tmp_label1); 
$table->put($j,3,$tmp_label2); 

push @ents, $tmp_label2;

$i++; 
} 

$table->pack( -expand=>1 , -fill=>'both'); 


my $button_frame = $mw->Frame( -borderwidth => 4 )->pack(); 
$button_frame->Button(-text => "Exit", -command => sub {exit})->pack()
+; 

&defineOrder( @ents );

MainLoop; 

sub defineOrder
{
    my $widget;
    for (my $i=0; defined( $_[$i+1] ); $i++)
    {
      $_[$i]->bind( '<Key-Return>', [\&focus, $_[$i+1]]);
      $_[$i]->bind( '<Tab>', [\&focus, $_[$i+1]]);
    }

    # Uncomment this line if you want to wrap around
    $_[ $#_ ]->bind('<Key-Return>',  [\&focus, $_[0]]);
    $_[ $#_ ]->bind('<Tab>',  [\&focus, $_[0]]);

    $_[0]->focus;
}



sub focus
{
    my ($tk, $self) = @_;
    $self->focus;
}
[download]

Thank you very much..