use warnings;
use strict;

sub test {
    my %email_of;
    my @name  = qw(Joe mary ann pete amy jerry);
    my @email = qw(joe@test.com mary@test.com ann@nowhere.com pete@her
+e.com amy@ok.com jerry@b.com);

    for my $i (0 .. $#name) {
        $email_of{$name[$i]} = $email[$i];
    }
    return \%email_of;
}

my $info = test();
foreach my $all (%$info) {
    print "$all\n";
}
[download]

Even fancier (see perldata):

sub test {
    my @name  = qw(Joe mary ann pete amy jerry);
    my @email = qw(joe@test.com mary@test.com ann@nowhere.com pete@her
+e.com amy@ok.com jerry@b.com);

    my %email_of;
    @email_of{@name} = @email;
    return \%email_of;
}
[download]