gopalr u can try the following or u can use substr,

use Win32::OLE;
use Win32::OLE qw(in with);
use Win32::OLE::Const 'Microsoft Word';
$word=Win32::OLE->GetActiveObject('Word.Application');
$doc= $word->activedocument;
$rng = $doc->{range};
$rng->select;
$a = $rng->text;
$a='This is Sample Pre Match Text<web>www.hotmail.com</web>This is Sam
+ple Post Match Text';
$a =~ m|<web>www\.hotmail\.com<\/web>|si;
$pre= $`;$post= $';

($pretext)= $pre =~ /(.{15})$/i; 
($posttext)= $pre =~ /^(.{15})/i; 

print "pre:$pre\npost:$post\n";
print "\n\n";
print "pre:$pretext\npost:$posttext\n";
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