LD_PRELOAD_64=/usr/sfw/lib/64/libssl.so does work.
Sounds like libssl.so is not being linked in, so you might need to add "-lssl -lcrypto" to the LDLOADLIBS line in the Makefile: 
LDLOADLIBS = -lz -L/usr/sfw/lib/64 -lssl -lcrypto

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In reply to Re: Relocation errors in Crypt::SSLeay in Solaris 10 by hazylife
in thread Relocation errors in Crypt::SSLeay in Solaris 10 by arielCo

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