Such a problem with Mozilla::CA should result in "certificate verify failed" rather than just the generic "can't connect" error. Here's what I see when I force that (host redacted):

Error GETing https://HOST/: Can't connect to HOST:443 (certificate verify failed)

Note that this isn't on MS Windows.

🦛

In reply to Re^2: WWW::Mechanize cannot connect to HTTPS site by hippo
in thread WWW::Mechanize cannot connect to HTTPS site by Marshall

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