in reply to How can i send email to Multiple email addresses using Email::Simple

  1. From says who send the mail. So, adding addresses to the From header doesn't get your mail delivered multiple times.
  2. Why ask if something is possible? Why don't you try and see?
  3. Did you read the documentation of Email::Simple?
  4. You probably need the 'Cc' header. Read the manual page how to set it.
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